José Gregorio Hernández - Graduated in 1888, renowned Venezuelan physician and researcher, known for his work in bacteriology and his candidacy for sainthood.
Andrés Bello - Graduated in 1800, a key figure in Latin American literature, law, and politics, founder of the Universidad de Chile.
Simón Bolívar - Attended in the early 19th century, leader of several independence movements in South America, known as 'El Libertador'.
Teresa de la Parra - Graduated in 1910, influential Venezuelan writer, known for her novels 'Ifigenia' and 'Mama Blanca's Memoirs'.