Andrés Eloy Blanco - Graduated in 1926, a prominent Venezuelan poet and politician.
Jacinto Convit - Graduated in 1938, renowned for his work on leprosy and leishmaniasis, awarded the Prince of Asturias Award for Technical and Scientific Research.
Teresa de la Parra - Attended in the early 20th century, a celebrated Venezuelan novelist.
Adolfo Pacheco - Graduated in 1950, a notable Venezuelan composer and musician.