María Corina Machado - Venezuelan politician and businesswoman, graduated from Universidad Pedagógica Experimental Libertador. Known for her advocacy for democracy and human rights.
Antonio Ecarri - Venezuelan lawyer and politician, alumnus of UPEL. He has been involved in educational reform and political activism.
Leonardo Carvajal - Educator and researcher, graduated from UPEL. Recognized for contributions to educational policy in Venezuela.
María Guzmán - Noted for her work in educational psychology, alumna of Universidad Pedagógica Experimental Libertador. She has published extensively on child development.