Cardinal Antonio Cañizares Llovera - Graduated in 1970, served as Archbishop of Valencia and Prefect of the Congregation for Divine Worship and the Discipline of the Sacraments.
Msgr. José Ignacio Munilla Aguirre - Graduated in 1989, Bishop of Orihuela-Alicante, known for his work in theological education.
Msgr. Juan Antonio Reig Pla - Graduated in 1980, Bishop of Alcalá de Henares, noted for his contributions to pastoral care.
Msgr. Francisco Cases Andreu - Graduated in 1984, Auxiliary Bishop of Madrid, recognized for his work in evangelization.